用于生物探针的糖胺聚糖中磷酸化和硫酸化糖基丝氨酸的立体选择性合成。
Stereoselective syntheses of phosphorylated and sulfated glycosyl serines in glycosaminoglycan for biological probes.
作者信息
Tamura J, Nishihara J
机构信息
Department of Environmental Sciences, Faculty of Education & Regional Sciences, Tottori University, Japan.
出版信息
Bioorg Med Chem Lett. 1999 Jul 19;9(14):1911-4. doi: 10.1016/s0960-894x(99)00300-5.
Abstract
Phosphorylated glycosyl serines of glycosaminoglycan with/without sulfate: beta-D-Xyl(2P)-Ser (1) and beta-D-Gal(+/-6S)-(1->4)-beta-D-Xyl(2P)-Ser (2, 3) were suitably designed for biological probes. These oligosaccharides were synthesized in a stereocontrolled manner.
摘要
含/不含硫酸酯的糖胺聚糖的磷酸化糖基丝氨酸：β-D-木糖（2-磷酸）-丝氨酸（1）和β-D-半乳糖（±6-硫酸酯）-（1→4）-β-D-木糖（2-磷酸）-丝氨酸（2,3）被适当地设计用于生物探针。这些寡糖以立体控制的方式合成。
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