Inagaki M, Isobe R, Miyamoto T, Higuchi R
Faculty of Pharmaceutical Sciences, Kyushu University, Fukuoka, Japan.
Chem Pharm Bull (Tokyo). 1999 Aug;47(8):1184-7. doi: 10.1248/cpb.47.1184.
Collision-induced dissociation (CID) spectra of sodium ion complexes ([M+Na]+ ions), produced by FAB-MS of methyl ester derivatives of ganglioside, indicate the length of the fatty acyl chain of the ceramide moieties without chemical degradation. In the case of a genuine ganglioside, only the fission of the glycosyl linkage of sialic acid was prominently observed.
通过神经节苷脂甲酯衍生物的快原子轰击质谱（FAB-MS）产生的钠离子复合物（[M + Na]+离子）的碰撞诱导解离（CID）光谱，可在不发生化学降解的情况下表明神经酰胺部分的脂肪酰链长度。对于真正的神经节苷脂，仅显著观察到唾液酸糖基键的断裂。
