Sugiyama H, Nitta T, Horii M, Motohashi K, Sakai J, Usui T, Hisamichi K, Ishiyama J I
Institute for Chemical Reaction Science, Tohoku University, Sendai, Japan.
Carbohydr Res. 2000 Apr 20;325(3):177-82. doi: 10.1016/s0008-6215(99)00310-9.
The conformation of maltose-type oligomers in water and in dimethylsulfoxide (Me2SO) was studied using two-dimensional NMR spectra. In Me2SO all of the oligomers have a 1a-type conformation. In water, they tend to adopt the same conformation, but the oligomers are looser and more flexible than in Me2SO.