Fluoroacrylate-bound fluorous-phase soluble hydrogenation catalysts.
作者信息
Bergbreiter DE, Franchina JG, Case BL
机构信息
Department of Chemistry, Texas A&M University, College Station 77842-3012, USA.
出版信息
Org Lett. 2000 Feb 10;2(3):393-5. doi: 10.1021/ol991352h.
PMID:10814331
Abstract
[reaction: see text] Fluoroacrylate polymer-bound hydrogenation catalysts are described. N-Acryloxysuccinimide-containing fluoroacrylate polymers were converted into phosphine ligands and subsequently into analogues of Wilkinson's catalyst by amidation of N-acryloxysuccinimide active ester residues and Rh exchange. The resulting catalysts have excellent activity and can be reused following fluorous biphasic liquid/liquid separation and extraction.
摘要
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