De Feyter S, Gesquière A, Abdel-Mottaleb M M, Grim P C, De Schryver F C, Meiners C, Sieffert M, Valiyaveettil S, Müllen K
Max-Planck-Institut für Polymerforschung, Ackermannweg 10, D-55128 Mainz, Germany.
Acc Chem Res. 2000 Aug;33(8):520-31. doi: 10.1021/ar970040g.
Scanning tunneling microscopy (STM) is applied to study organic monolayers, physisorbed at the liquid-graphite interface. Due to the very local nature of the probing, the structure of these adlayers has been imaged with very high detail. The high resolution allowed us to investigate the effect of molecular chirality on the monolayer formation and provided a unique way to study chemical reactions at the liquid-graphite interface. Making use of a fast scanning mode, dynamic processes in these adlayers have been visualized.
扫描隧道显微镜(STM)被应用于研究物理吸附在液-石墨界面的有机单层。由于探测具有非常局部的性质,这些吸附层的结构已被非常详细地成像。高分辨率使我们能够研究分子手性对单层形成的影响,并提供了一种研究液-石墨界面化学反应的独特方法。利用快速扫描模式,这些吸附层中的动态过程已被可视化。