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自组装物理吸附单分子层中分子手性表达的丧失。

Losing the expression of molecular chirality in self-assembled physisorbed monolayers.

作者信息

Zhang Jian, Gesquière André, Sieffert Michel, Klapper Markus, Müllen Klaus, De Schryver Frans C, De Feyter Steven

机构信息

Molecular and Nano Materials, Laboratory of Photochemistry and Spectroscopy, Department of Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200 F, B-3001 Leuven, Belgium.

出版信息

Nano Lett. 2005 Jul;5(7):1395-8. doi: 10.1021/nl050717q.

DOI:10.1021/nl050717q
PMID:16178245
Abstract

STM imaging on graphite of the S-enantiomer of a chiral diacetylene isophthalic acid derivative reveals that molecular chirality is not expressed in the monolayer due to a specific molecular conformation preventing the stereogenic center to transfer its chiral information.

摘要

在手性二乙炔间苯二甲酸衍生物的 S-对映体的石墨上进行扫描隧道显微镜(STM)成像显示,由于特定的分子构象阻止了手性中心传递其手性信息,分子手性在单层中未表现出来。

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