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不稳定方向在过冷液体平衡和老化动力学中的作用。

Role of unstable directions in the equilibrium and aging dynamics of supercooled liquids.

作者信息

Donati C, Sciortino F, Tartaglia P

机构信息

Dipartimento di Fisica, Universita' di Roma "La Sapienza", Istituto Nazionale per la Fisica della Materia, Piazzale Aldo Moro 2, I-00185, Roma, Italy.

出版信息

Phys Rev Lett. 2000 Aug 14;85(7):1464-7. doi: 10.1103/PhysRevLett.85.1464.

Abstract

The connectivity of the potential energy landscape in supercooled atomic liquids is investigated through a calculation of the instantaneous normal modes spectrum and a detailed analysis of the unstable directions in configuration space. We confirm the hypothesis that the mode-coupling critical temperature is the T at which the dynamics crosses over from free to activated exploration of configuration space. We also observe changes in the local connectivity of configuration space sampled during aging, following a temperature jump from a liquid to a glassy state.

摘要

通过计算瞬时简正模式谱并详细分析构型空间中的不稳定方向,研究了过冷原子液体中势能面的连通性。我们证实了模式耦合临界温度是动力学从构型空间的自由探索转变为激活探索时的温度这一假设。我们还观察到,在温度从液态跃升至玻璃态后,老化过程中采样的构型空间局部连通性的变化。

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