• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

非氢负离子中双激发态的自脱离

Autodetachment of doubly excited states in nonhydrogenic negative ions.

作者信息

Kiyan I Y

机构信息

Department of Physics, Chalmers University of Technology and Göteborg University, SE-412 96 Göteborg, Sweden.

出版信息

Phys Rev Lett. 2000 Jun 26;84(26 Pt 1):5975-8. doi: 10.1103/PhysRevLett.84.5975.

DOI:10.1103/PhysRevLett.84.5975
PMID:10991102
Abstract

A semiclassical model is developed to describe the two-electron dynamics of the process of autodetachment. A formula derived for the partial width of a doubly excited state represents a product of an amplitude and phase factors. An anomalous width behavior is predicted for states near a threshold when the orbital angular momentum of the outer electron is high. Oscillations of the phase factor, as a function of energy, determine the functional behavior of relative widths in the region farther from threshold for a given series of states.

摘要

开发了一种半经典模型来描述自电离过程的双电子动力学。为双激发态的部分宽度推导的公式表示振幅和相位因子的乘积。当外层电子的轨道角动量较高时,预测接近阈值的状态会出现异常宽度行为。相位因子作为能量的函数的振荡决定了给定系列状态在远离阈值区域中相对宽度的函数行为。

相似文献

1
Autodetachment of doubly excited states in nonhydrogenic negative ions.非氢负离子中双激发态的自脱离
Phys Rev Lett. 2000 Jun 26;84(26 Pt 1):5975-8. doi: 10.1103/PhysRevLett.84.5975.
2
Spectrum of doubly excited states in the K- ion.钾离子中双激发态的光谱
Phys Rev Lett. 2000 Jun 26;84(26 Pt 1):5979-82. doi: 10.1103/PhysRevLett.84.5979.
3
Visualization of electron correlation in autoionizing states above the 3p threshold in magnesium.
Phys Chem Chem Phys. 2005 Sep 21;7(18):3276-83. doi: 10.1039/b508158k. Epub 2005 Aug 5.
4
Communication: angular momentum alignment and fluorescence polarization of alkali atoms photodetached from helium nanodroplets.通讯:氦纳米液滴光电离的碱金属原子的角动量取向和荧光偏振。
J Chem Phys. 2013 Dec 14;139(22):221102. doi: 10.1063/1.4843235.
5
Resonance Regge poles and the state-to-state F + H2 reaction: QP decomposition, parametrized S matrix, and semiclassical complex angular momentum analysis of the angular scattering.共振 Regge 极点与态态 F+H2 反应:QP 分解、参数化 S 矩阵及角散射的半经典复角动量分析
J Chem Phys. 2013 Mar 28;138(12):124310. doi: 10.1063/1.4794859.
6
Two-electron Rabi oscillations in real-time time-dependent density-functional theory.实时含时密度泛函理论中的双电子拉比振荡
J Chem Phys. 2014 Nov 14;141(18):184112. doi: 10.1063/1.4900514.
7
High-resolution millimeter wave spectroscopy and multichannel quantum defect theory of the hyperfine structure in high Rydberg states of molecular hydrogen H2.分子氢H₂高里德堡态超精细结构的高分辨率毫米波光谱学与多通道量子亏损理论
J Chem Phys. 2004 Dec 15;121(23):11810-38. doi: 10.1063/1.1792596.
8
Doublet-quartet conversion in negative ions as a possible mechanism of the electron autodetachment delay.负离子中的双重态-四重态转换作为电子自脱附延迟的一种可能机制。
Rapid Commun Mass Spectrom. 2006;20(24):3699-708. doi: 10.1002/rcm.2792.
9
Modeling the doubly excited state with time-dependent Hartree-Fock and density functional theories.用时变哈特里-福克理论和密度泛函理论对双激发态进行建模。
J Chem Phys. 2008 Nov 28;129(20):204107. doi: 10.1063/1.3020336.
10
On the Competition Between Electron Autodetachment and Dissociation of Molecular Anions.关于电子自动脱离与分子阴离子解离的竞争。
J Am Soc Mass Spectrom. 2019 Oct;30(10):1828-1834. doi: 10.1007/s13361-019-02237-z. Epub 2019 May 28.