通过使用(2R, 6S)-7-乙酰氧基-2,6-二甲基-1-庚醇作为起始原料对米蛾和椿象信息素进行新的合成。
New syntheses of the rice moth and stink bug pheromones by employing (2R, 6S)-7-acetoxy-2,6-dimethyl-1-heptanol as a building block.
作者信息
Nakamura Y, Mori K
机构信息
Department of Chemistry, Faculty of Science, Science University of Tokyo, Japan.
出版信息
Biosci Biotechnol Biochem. 2000 Aug;64(8):1713-21. doi: 10.1271/bbb.64.1713.
PMID:10993161
Abstract
(2R, 6R, 10R)-6,10,14-Trimethyl-2-pentadecanol, the female pheromone of the rice moth (Corcyra cephalonica), methyl (2R, 6R, 10R)-2,6,10-trimethyltridecanoate, the male pheromone of the stink bug (Euschistus heros) were synthesized by employing (2R, 6S)-7-acetoxy-2,6-dimethyl-1-heptanol as the common chiral building block.
摘要
(2R, 6R, 10R)-6,10,14-三甲基-2-十五烷醇，即米蛾（Corcyra cephalonica）的雌性信息素，以及(2R, 6R, 10R)-2,6,10-三甲基十三烷酸甲酯，即椿象（Euschistus heros）的雄性信息素，均以(2R, 6S)-7-乙酰氧基-2,6-二甲基-1-庚醇作为常见的手性结构单元合成得到。
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