Otero L, Sanz P D
Instituto del Frío (CSIC), Ciudad Universitaria, 28040 Madrid, Spain.
Biotechnol Prog. 2000 Nov-Dec;16(6):1030-6. doi: 10.1021/bp000122v.
A mathematical model to calculate the amount of ice formed instantaneously after a rapid expansion in high-pressure shift processes (HPSF) was developed. It considers that when water is expanded it does not extend over its melting curve but reaches a metastable state (supercooled water), which also occurs in practice. Theoretical results appear to agree with experimental data.
建立了一个数学模型,用于计算高压变换过程(HPSF)中快速膨胀后瞬间形成的冰量。该模型认为,水在膨胀时不会越过其熔化曲线,而是达到一种亚稳态(过冷水),这在实际中也会发生。理论结果似乎与实验数据相符。