Rosenfeld Y
Nuclear Research Center Negev, P.O. Box 9001, Beer-Sheva 84190, Israel.
Phys Rev E Stat Phys Plasmas Fluids Relat Interdiscip Topics. 2000 Nov;62(5 Pt B):7524-7. doi: 10.1103/physreve.62.7524.
A semiempirical "universal" corresponding states relationship, for the dimensionless transport coefficients of dense fluids as functions of the reduced configurational entropy, was proposed more than 20 years ago and established by many simulations. Recent density functional analysis predicts a universal freezing-temperature scaling for the excess entropy. Combining these properties we derive an approximate corresponding states relationship for the dimensionless transport coefficients of dense fluids as functions of the temperature scaled by the freezing temperature. The temperature scaling observed in recent computer simulation results for self-diffusion in Yukawa systems is just one more case of our general result.
二十多年前提出了一种半经验的“通用”对应态关系，用于描述稠密流体的无量纲输运系数与约化构型熵的函数关系，并且通过许多模拟得到了证实。最近的密度泛函分析预测了过剩熵的通用冻结温度标度。结合这些性质，我们推导出了一种近似的对应态关系，用于描述稠密流体的无量纲输运系数与以冻结温度标度的温度的函数关系。最近在汤川系统中自扩散的计算机模拟结果中观察到的温度标度只是我们一般结果的又一个例子。
