Teng H, Lin Y C, Hsu L Y
Department of Chemical Engineering, National Cheng Kung University, Tainan, Taiwan.
J Air Waste Manag Assoc. 2000 Nov;50(11):1940-6. doi: 10.1080/10473289.2000.10464221.
Activated carbons were produced from waste tires using a chemical activation method. The carbon production process consisted of potassium hydroxide (KOH) impregnation followed by pyrolysis in N2 at 600-900 degrees C for 0-2 hr. The activation method can produce carbons with a surface area (SA) and total pore volume as high as 470 m2/g and 0.57 cm3/g, respectively. The influence of different parameters during chemical activation, such as pyrolysis temperature, holding time, and KOH/tire ratio, on the carbon yield and the surface characteristics was explored, and the optimum preparation conditions were recommended. The pore volume of the resulting carbons generally increases with the extent of carbon gasified by KOH and its derivatives, whereas the SA increases with degree of gasification to reach a maximum value, and then decreases upon further gasification.
采用化学活化法从废旧轮胎中制备活性炭。碳的生产过程包括氢氧化钾(KOH)浸渍,然后在600 - 900℃的氮气中热解0 - 2小时。该活化方法可制备出表面积(SA)高达470 m²/g、总孔体积高达0.57 cm³/g的碳。探讨了化学活化过程中不同参数(如热解温度、保温时间和KOH/轮胎比)对碳产率和表面特性的影响,并推荐了最佳制备条件。所得碳的孔体积通常随着被KOH及其衍生物气化的碳的程度而增加,而SA随着气化程度增加达到最大值,然后在进一步气化时降低。