• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

1/2V2O5 - H2C2O4/H3PO4/NH4OH体系的水热研究：(NH4)VOPO(4).1.5H2O、(NH4)0.5VOPO(4).1.5H2O、(NH4)2[VO(H2O)3]2[VO(H2O)][VO(PO4)2](2).3H2O和(NH4)2[VO(HPO4)]2(C2O4).5H2O的合成与结构

A hydrothermal investigation of the 1/2V2O5-H2C2O4/H3PO4/NH4OH system: synthesis and structures of (NH4)VOPO(4).1.5H2O, (NH4)0.5VOPO(4).1.5H2O, (NH4)2[VO(H2O)3]2[VO(H2O)][VO(PO4)2](2).3H2O, and (NH4)2[VO(HPO4)]2(C2O4).5H2O.

作者信息

Do J, Bontchev R P, Jacobson A J

机构信息

Department of Chemistry, University of Houston, Houston, Texas 77204-5641, USA.

出版信息

Inorg Chem. 2000 Jul 24;39(15):3230-7. doi: 10.1021/ic0000303.

DOI:10.1021/ic0000303
PMID:11196858
Abstract

The 1/2V2O5-H2C2O4/H3PO4/NH4OH system was investigated using hydrothermal techniques. Four new phases, (NH4)VOPO(4).1.5H2O (1), (NH4)0.5VOPO(4).1.5H2O (2), (NH4)2[VO(H2O)3]2[VO(H2O)][VO(PO4)2]2.3H2O (3), and (NH4)2[VO(HPO4)]2(C2O4).H2O (4), have been prepared and structurally characterized. Compounds 1 and 2 have layered structures closely related to VOPO(4).2H2O and A0.5VOPO4.yH2O (A = mono- or divalent metals), whereas 3 has a 3D open-framework structure. Compound 4 has a layered structure and contains both oxalate and phosphate anions coordinated to vanadium cations. Crystal data: (NH4)VOPO(4).1.5H2O, tetragonal (I), space group I4/mmm (No. 139), a = 6.3160(5) A, c = 13.540(2) A, Z = 4; (NH4)0.5VOPO(4).1.5H2O, monoclinic, space group P2(1)/m (No. 11), a = 6.9669(6) A, b = 17.663(2) A, c = 8.9304(8) A, beta = 105.347(1) degrees, Z = 8; (NH4)2[VO(H2O)3]2[VO(H2O)][VO(PO4)2]2.3H2O, triclinic, space group P1 (No. 2), a = 10.2523(9) A, b = 12.263(1) A, c = 12.362(1) A, alpha = 69.041(2) degrees, beta = 65.653(2) degrees, gamma = 87.789(2) degrees, Z = 2; (NH4)2[VO(HPO4)]2(C2O4).5H2O, monoclinic (C), space group C2/m (No. 12), a = 17.735(2) A, b = 6.4180(6) A, c = 22.839(2) A, beta = 102.017(2) degrees, Z = 6.

摘要

采用水热技术对1/2V2O5-H2C2O4/H3PO4/NH4OH体系进行了研究。制备并对四个新相(NH4)VOPO(4).1.5H2O (1)、(NH4)0.5VOPO(4).1.5H2O (2)、(NH4)2[VO(H2O)3]2[VO(H2O)][VO(PO4)2]2.3H2O (3)和(NH4)2[VO(HPO4)]2(C2O4).H2O (4)进行了结构表征。化合物1和2具有与VOPO(4).2H2O和A0.5VOPO4.yH2O（A = 一价或二价金属）密切相关的层状结构，而化合物3具有三维开放骨架结构。化合物4具有层状结构，并且含有与钒阳离子配位的草酸根和磷酸根阴离子。晶体数据：(NH4)VOPO(4).1.5H2O，四方晶系（I），空间群I4/mmm（编号139），a = 6.3160(5) Å，c = 13.540(2) Å，Z = 4；(NH4)0.5VOPO(4).1.5H2O，单斜晶系，空间群P2(1)/m（编号11），a = 6.9669(6) Å，b = 17.663(2) Å，c = 8.9304(8) Å，β = 105.347(1)°，Z = 8；(NH4)2[VO(H2O)3]2[VO(H2O)][VO(PO4)2]2.3H2O，三斜晶系，空间群P1（编号2），a = 10.2523(9) Å，b = 12.263(1) Å，c = 12.362(1) Å，α = 69.041(2)°，β = 65.653(2)°，γ = 87.789(2)°，Z = 2；(NH4)2[VO(HPO4)]2(C2O4).5H2O，单斜晶系（C），空间群C2/m（编号12），a = 17.735(2) Å，b = 6.4180(6) Å，c = 22.839(2) Å，β = 102.017(2)°，Z = 6。

相似文献

1
A hydrothermal investigation of the 1/2V2O5-H2C2O4/H3PO4/NH4OH system: synthesis and structures of (NH4)VOPO(4).1.5H2O, (NH4)0.5VOPO(4).1.5H2O, (NH4)2[VO(H2O)3]2[VO(H2O)][VO(PO4)2](2).3H2O, and (NH4)2[VO(HPO4)]2(C2O4).5H2O.1/2V2O5 - H2C2O4/H3PO4/NH4OH体系的水热研究：(NH4)VOPO(4).1.5H2O、(NH4)0.5VOPO(4).1.5H2O、(NH4)2[VO(H2O)3]2[VO(H2O)][VO(PO4)2](2).3H2O和(NH4)2[VO(HPO4)]2(C2O4).5H2O的合成与结构
Inorg Chem. 2000 Jul 24;39(15):3230-7. doi: 10.1021/ic0000303.
2
Hydrothermal synthesis, thermal, and magnetic data on new alkaline vanadium phosphate My(VO)9 + x(PO4)4x(HPO4)12 - 4x with M = Cs+ (y = 5.29, x = 1) and M = NH4+, Rb+ (y approximately 5, x approximately 1).关于新型碱金属钒磷酸盐My(VO)9 + x(PO4)4x(HPO4)12 - 4x（其中M = Cs+ （y = 5.29，x = 1）以及M = NH4+、Rb+ （y约为5，x约为1））的水热合成、热学和磁学数据。
Inorg Chem. 2001 Jan 15;40(2):272-6. doi: 10.1021/ic000464y.
3
Na2[(VO)2(HPO4)2C2O4].2H2O: crystal structure determination from combined powder diffraction and solid-state NMR.Na2[(VO)2(HPO4)2C2O4].2H2O：基于粉末衍射和固态核磁共振联用的晶体结构测定
Inorg Chem. 2006 Jul 24;45(15):6034-40. doi: 10.1021/ic060483t.
4
Syntheses and structures of two low-dimensional beryllium phosphate compounds: [C5H14N2]2[Be3(HPO4)5].H2O and [C6H18N2]0.5[Be2(PO4)(HPO4)OH].0.5H2O.两种低维磷酸铍化合物的合成与结构：[C5H14N2]2[Be3(HPO4)5].H2O 和 [C6H18N2]0.5[Be2(PO4)(HPO4)OH].0.5H2O
Inorg Chem. 2006 Apr 17;45(8):3281-6. doi: 10.1021/ic051906e.
5
Influence of hydrogen bonding on the assembly of six-membered vanadium borophosphate cluster anions: synthesis and structures of (NH4)2(C2H10N2)6[Sr(H2O)5]2[V2P2BO12](6)10H2O, (NH4)2(C3H12N2)6[Sr(H2O)4]2[V2P2BO12](6)17H2O, and (NH4)3(C4H14N2)4 5[Sr(H2O)5]2[Sr(H2O)4][V2P2BO12]6 10H2O.氢键对六元钒硼磷酸簇阴离子组装的影响：(NH4)2(C2H10N2)6[Sr(H2O)5]2[V2P2BO12](6)10H2O、(NH4)2(C3H12N2)6[Sr(H2O)4]2[V2P2BO12](6)17H2O和(NH4)3(C4H14N2)4 5[Sr(H2O)5]2[Sr(H2O)4][V2P2BO12]6 10H2O的合成与结构
Inorg Chem. 2000 Sep 18;39(19):4305-10. doi: 10.1021/ic000435n.
6
New layered uranium phosphate fluorides: syntheses, structures, characterizations, and ion-exchange properties of A(UO2)F(HPO4).xH2O (A = Cs+, Rb+, K+; x = 0-1).新型层状铀磷酸盐氟化物：A(UO2)F(HPO4).xH2O（A = Cs+、Rb+、K+；x = 0 - 1）的合成、结构、表征及离子交换性能
Inorg Chem. 2006 Dec 11;45(25):10207-14. doi: 10.1021/ic061420d.
7
Solid-state coordination chemistry: structural influences of copper-phenanthroline subunits on oxovanadium organophosphonate phases. hydrothermal synthesis and structural characterization of the two-dimensional materials [Cu(phen)(VO)(O3PCH2PO3)(H2O)], [[Cu(phen)]2(V2O5)(O3PCH2CH2PO3)], and [[Cu(phen)]2(V3O5)(O3PCH2CH2CH2PO3)2(H2O)] and the three-dimensional phase [[Cu(phen)]2(V3O5)(O3PCH2PO3)2(H2O)].固态配位化学：铜-菲咯啉亚基对氧钒有机膦酸盐相的结构影响。二维材料[Cu(phen)(VO)(O3PCH2PO3)(H2O)]、[[Cu(phen)]2(V2O5)(O3PCH2CH2PO3)]和[[Cu(phen)]2(V3O5)(O3PCH2CH2CH2PO3)2(H2O)]以及三维相[[Cu(phen)]2(V3O5)(O3PCH2PO3)2(H2O)]的水热合成与结构表征
Inorg Chem. 2001 Jul 16;40(15):3745-54. doi: 10.1021/ic010186i.
8
Radical salts of bis(ethylenediseleno)tetrathiafulvalene with paramagnetic tris(oxalato)metalate anions.双（乙二硒）四硫富瓦烯与顺磁性三（草酸根）金属酸根阴离子形成的自由基盐。
Inorg Chem. 2006 Dec 25;45(26):10815-24. doi: 10.1021/ic061494p.
9
Synthesis, structural and spectroscopic properties of two new ethylenediamine-templated gallophosphate-oxalate layered materials.两种新型乙二胺模板化的镓磷酸盐 - 草酸盐层状材料的合成、结构及光谱性质
Inorg Chem. 2003 Jan 27;42(2):598-604. doi: 10.1021/ic025663r.
10
The series of molecular conductors and superconductors ET4[AFe(C2O4)3]·PhX (ET = bis(ethylenedithio)tetrathiafulvalene; (C2O4)2- = oxalate; A+ = H3O+, K+; X = F, Cl, Br, and I): influence of the halobenzene guest molecules on the crystal structure and superconducting properties.一系列分子导体和超导体 ET4[AFe(C2O4)3]·PhX（ET = 双（乙二硫代）四硫富瓦烯；(C2O4)2- = 草酸根；A+ = H3O+，K+；X = F，Cl，Br，I）：卤代苯客体分子对晶体结构和超导性能的影响。
Inorg Chem. 2012 Jan 16;51(2):1111-26. doi: 10.1021/ic202269x. Epub 2011 Dec 23.

引用本文的文献

1
Effect of Layered Aminovanadic Oxalate Phosphate on Flame Retardancy of Epoxy Resin.层状氨基钒酸氧代磷酸酯对环氧树脂阻燃性能的影响。
Molecules. 2023 Apr 9;28(8):3322. doi: 10.3390/molecules28083322.