Nakano T
Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST), Ikoma, Japan.
J Chromatogr A. 2001 Jan 12;906(1-2):205-25. doi: 10.1016/s0021-9673(00)00944-4.
Synthetic, optically active polymers used as CSP are reviewed. The polymers are classified into three major categories, namely, addition polymers, condensation polymers, and cross-linked gels. The emphasis lies on polymethacrylates having helical conformation belonging to the first category. Helical polymethacrylates are synthesized using asymmetric anionic or radical polymerization techniques and show resolving ability towards a wide range of racemate.
综述了用作手性固定相的合成光学活性聚合物。这些聚合物分为三大类，即加聚物、缩聚物和交联凝胶。重点在于属于第一类的具有螺旋构象的聚甲基丙烯酸酯。螺旋聚甲基丙烯酸酯是使用不对称阴离子或自由基聚合技术合成的，并且对多种外消旋体显示出拆分能力。
