六（三氟甲基）环三磷腈的一种新合成方法。N3P3(CF3)6和N3P3F6的单晶X射线结构。

A novel synthesis of hexakis(trifluoromethyl)cyclotriphosphazene. Single-crystal X-ray structures of N3P3(CF3)6 and N3P3F6.

作者信息

Singh R P, Vij A, Kirchmeier R L, Shreeve J M

机构信息

Department of Chemistry, University of Idaho, Moscow 83844-2343, USA.

出版信息

Inorg Chem. 2000 Jan 24;39(2):375-7. doi: 10.1021/ic9909781.

DOI:10.1021/ic9909781

PMID:11272550

Abstract

Reaction of hexafluorocyclotriphosphazene (N3P3F6) with trimethyl(trifluoromethyl)silane in the presence of a catalytic amount of cesium fluoride in THF produced hexakis(trifluoromethyl)cyclotriphosphazene [N3P3(CF3)6] in 90% isolated yield. N3P3(CF3)6 is fully characterized by melting point, IR, NMR (19F, 13C, 31p), MS, and elemental analysis data. Single-crystal X-ray structures of N3P3(CF3)6 and N3P3F6 are reported.

摘要

六氟环三磷腈（N3P3F6）与三甲基（三氟甲基）硅烷在四氢呋喃中，于催化量的氟化铯存在下反应，以90%的分离产率生成了六（三氟甲基）环三磷腈[N3P3(CF3)6]。通过熔点、红外光谱、核磁共振（19F、13C、31P）、质谱和元素分析数据对N3P3(CF3)6进行了全面表征。报道了N3P3(CF3)6和N3P3F6的单晶X射线结构。