一种用于引入三氟甲基的黄原酸酯转移自由基过程。
A xanthate transfer radical process for the introduction of the trifluoromethyl group.
作者信息
Bertrand F, Pevere V, Quiclet-Sire B, Zard S Z
机构信息
Institut de Chimie des Substances Naturelles, C.N.R.S., 91198 Gif-sur-Yvette, France.
出版信息
Org Lett. 2001 Apr 5;3(7):1069-71. doi: 10.1021/ol0156446.
PMID:11277797
Abstract
[reaction: see text]. S-Trifluoromethyl xanthates efficiently add to unactivated alkenes by a radical mechanism to give adducts with a trifluoromethyl group at the least hindered terminus of the olefin.
摘要
[反应：见正文]。S-三氟甲基黄原酸酯通过自由基机理有效地加成到未活化的烯烃上，在烯烃位阻最小的末端生成带有三氟甲基的加合物。
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