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Macromolecule-Induced Clustering of Hard Spheres.

作者信息

Chatterjee Avik Prasun

机构信息

Department of Chemistry, Edwin C. Jahn Laboratory, SUNY-ESF, One Forestry Drive, Syracuse, New York, 13210

出版信息

J Colloid Interface Sci. 2001 Jun 1;238(1):125-128. doi: 10.1006/jcis.2001.7481.

DOI:10.1006/jcis.2001.7481
PMID:11350145
Abstract

The connectivity Ornstein-Zernike formalism, together with the polymer reference interaction site model (PRISM), is employed to describe connectivity and network formation in mixtures of spheres and polymers. Results are presented for the percolation of spheres induced by both flexible coil-like and rigid rod-like linear polymers; the Percus-Yevick (PY) approximation is used throughout. Our results are compared with predictions based on the adhesive hard sphere (AHS) model, and correlations with the polymer-mediated second virial coefficient between spheres are discussed. Copyright 2001 Academic Press.

摘要

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