Kapinus E I, Ivnitskaia I N, Dilung I I
Biofizika. 1975 May-Jun;20(3):411-3.
The quenching of the fluorescence of chlorophyll, Zn- and Cd-pheophytinates, Mg-, Zn-, Cd-, Al-, Ga-, In-, Hf-tetraphenylporphine in different solvents with chlorinanyl, p-benzoquinone and m-dinitrobenzole has been studied. It is concluded from the dependence of quenching on medium viscosity that static and kinamatic mechanisms are in the basis of quenching. The first one dominates within the high values of viscosity, the latter within the law ones. In case of metals on one group the quenching constants are decreased with the growth of the ordinal number of the central atom. This fact supports the great role of the dynamic factor during the quenching of fluorescence of tetrapirrole pigments.
研究了在不同溶剂中，二氢卟吩、对苯醌和间二硝基苯对叶绿素、锌-和镉-脱镁叶绿素、镁-、锌-、镉-、铝-、镓-、铟-、铪-四苯基卟啉荧光的猝灭作用。根据猝灭对介质粘度的依赖性得出结论，静态和动态机制是猝灭的基础。前者在高粘度值范围内占主导，后者在低粘度值范围内占主导。对于同一族中的金属，猝灭常数随着中心原子序数的增加而降低。这一事实支持了动态因素在四吡咯色素荧光猝灭过程中的重要作用。
