Saksena M. D., Deo M. N.
Spectroscopy Division, Modular Laboratories, Bhabha Atomic Research Center, Trombay, Mumbai, 400 085, India
J Mol Spectrosc. 2001 Jul;208(1):64-71. doi: 10.1006/jmsp.2001.8353.
For the first time, the emission spectrum of A(3)Pi(0)-X(1)Sigma(+) band system of InCl molecule has been recorded on BOMEM DA8 Fourier transform spectrometer at an apodized resolution of 0.025 cm(-1). The rotational structure of 1-0, 2-1, 0-0, 0-1, 1-2, 0-2, and 1-3 bands belonging to the A(3)Pi(0)-X(1)Sigma(+) transition of In(35)Cl has been analyzed and accurate equilibrium rotational constants of the A(3)Pi(0) state obtained. It has also been possible to unambiguously assign rotational lines of 1-0, 0-0, and 0-1 bands belonging to In(37)Cl isotopomer. No perturbations have been observed contrary to what has been reported by some of the earlier workers. Copyright 2001 Academic Press.
首次在BOMEM DA8傅里叶变换光谱仪上以0.025 cm⁻¹的变迹分辨率记录了InCl分子A(³Π₀)-X(¹Σ⁺)带系的发射光谱。分析了属于In³⁵Cl的A(³Π₀)-X(¹Σ⁺)跃迁的1-0、2-1、0-0、0-1、1-2、0-2和1-3带的转动结构，并获得了A(³Π₀)态精确的平衡转动常数。还能够明确归属属于In³⁷Cl同位素异构体的1-0、0-0和0-1带的转动谱线。与一些早期工作者所报道的情况相反，未观察到微扰现象。版权所有2001年学术出版社。
