Sorption of 1-naphthol to soil and geologic samples with varying diagenetic properties.

Remediation of contaminated land requires a firm understanding of the processes that occur between xenobiotics and soil colloids. It is currently accepted that the extent of xenobiotic uptake is proportional to the carbon quantity and character of the soil or geologic sample. Previous studies have developed empirical equations to predict the extent of sorption based on the aromatic carbon content. We examined these relationships with an independent set of soil and geologic samples and 1-naphthol. The 1-naphthol sorption coefficients varied significantly (P < 0.01) among sorbents and are consistent with the diagenetic properties of the organic matter in these samples. The cross-polarization magic angle spinning (CPMAS) 13C nuclear magnetic resonance (NMR) and elemental data did not concur with the sorption data for most of the soil samples. We suggest that this contradiction may be due to a third variable, the physical organization of the organic matter. Chemical methods measure the whole sample, whereas short-term sorption occurs on the surface; therefore, only some organic matter domains in the soil are available for interaction with 1-naphthol. Hence, chemical data alone may be insufficient for predicting the sorption behavior of xenobiotics in soil and geologic samples.