Maniukiewicz W, Bukowska-Strzyzewska M
Institute of General and Ecological Chemistry, Technical University of Lódz, Zwirki 36, 90-924 Lódz, Poland.
Acta Crystallogr C. 2001 Aug;57(Pt 8):889-90. doi: 10.1107/s0108270101006060. Epub 2001 Aug 9.
In the title compound, Cu(C(13)H(9)NO(3))(H(2)O), the Cu(II) ion is in a slightly distorted square-pyramidal environment, with four short bonds in the basal plane formed by three donor atoms of the Schiff base and a water O atom. A symmetry-related neighbouring molecule provides an apical carboxylate O atom at a distance of 2.551 (3) A; this contact leads to the formation of zigzag polymeric chains. In addition, the chain fragments are connected to each other by hydrogen bonding.
在标题化合物[Cu(C₁₃H₉NO₃)(H₂O)]ₙ中，Cu(II)离子处于略微扭曲的四方锥环境中，在由席夫碱的三个供体原子和一个水O原子形成的基面中有四个短键。一个对称相关的相邻分子提供了一个距离为2.551(3) Å的顶端羧酸根O原子；这种接触导致形成锯齿状聚合物链。此外，链片段通过氢键相互连接。
