Radhakrishnan U, Schweiger M, Stang P J
Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, USA.
Org Lett. 2001 Oct 4;3(20):3141-3. doi: 10.1021/ol0164684.
[reaction: see text] The simple combination of two angular tritopic pyridine donor linkers (109 degrees bond angle) with three ditopic platinum acceptors (90 degrees bond angle) leads to essentially quantitative formation of self-assembled M(3)L(2) trigonal-bipyramidal (TBP) supramolecular species.
[反应:见正文] 两个角形三齿吡啶供体连接体(键角109°)与三个双齿铂受体(键角90°)的简单组合基本上定量地形成了自组装的M(3)L(2)三角双锥(TBP)超分子物种。