Residues of methoxychlor and other chlorinated hydrocarbons in water, sand, and selected fauna following injections of methoxychlor black fly larvicide into the Saskatchewan River, 1972.

In May 1972, 0.309 ppm methoxychlor black fly larvicide was applied in a single test on the North Saskatchewan River. Eight to nine days later residues of 0.05-0.10 ppm methoxychlor occurred in sand 21-22 km downstream from the point of injection. Methoxychlor was not detected in water, insect larvae, shellfish, or muscle tissues of three fish species on the same sampling date. Perhaps because of relatively high oil content in goldeye fish, methoxychlor residues in muscle tissues were 1.0-1.5 ppm in 8 percent of those sampled, 0.21-0.99 in 21 percent, and 0.02-0.20 in 37 percent. In 34 percent of the goldeye fish no residues were detected. Goldeye and other fish collected before or 17 weeks after this injection did not contain detectable levels of methoxychlor. River water in two samples of the injected slug of water collected 6.5 km downstream from the point of injection contained 0.14 and 0.16 ppm methoxychlor. The suspended solids filtered from these sample contained 40 and 47 percent of this methoxychlor (437 and 892 ppm, respectively). Thus methoxychlor may act selectively against filter-feeding species, especially black fly larvae.