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[液晶是活的生物体吗?]

[Are liquid crystals living organisms?].

作者信息

Snelders H A

出版信息

Gewina. 1997;20(3):129-42.

Abstract

In 1888 the Austrian botanist F. Reinitzer made the observation that the solid compound cholesteryl-benzoate changes - when melting at 145.5 oC - into a cloudy liquid, that however, turns into a clear liquid at 178.5 oC and higher temperatures. The cloudy liquid seemed to be doubly refracting. Soon a number of these so-called 'liquid crystals' were discovered; in 1908 D. Vorländer, professor of organic chemistry at Halle, described more than 250 of these substances. It was O. Lehmann, professor of physics at Aachen (1885), Dresden (1888) and Karlsruhe (1889), who immediately after Reinitzer's observation began a systematic study of these liquid crystals. In The Netherlands the Amsterdam professor of physican chemistry H. W. Bakhuis Roozeboom was interested in liquid crystals, in particular because of their place in his phase system. F.M. Jaeger, at that time teaching chemistry in a secondary school in Zaandam (near Amsterdam) and working as an unpaid university lecturer at the Amsterdam university (by recommendation of Bakhuis Roozeboom), investigated liquid crystals (1906), as did a number of doctoral students (A.C. de Kock, 1903; A. Prins, 1907). At the university of Utrecht L.S. Ornstein, professor of physics, gave the study of liquid crystals a prominent place in his research programme. The discovery of liquid crystals, which seemed to be able to grow, move, divide, copulate, and so on, led to a discussion on the nature of these substances. Time and again Lehmann called them 'apparently living crystals', although without considering them as 'real living beings'. In his book Flüssige Kristalle und die Theorien des Lebens (1906), Lehmann proved to be an obvious adherent of the monistic views of the biologist E. Haeckel. Haeckel considered the existence of liquid crystals as proof of the unity between the inorganic and the organic world that he believed in so strongly. In his last book, Kristallseelen. Studien über das Anorganische Leben (1917), he considered liquid crystals a real form of life, as did F. Rinne, professor of mineralogy and petrography, as late as in the nineteen thirties.

摘要

1888年,奥地利植物学家F. 雷尼泽观察到,固态化合物胆固醇苯甲酸酯在145.5摄氏度熔化时会变成浑浊的液体,但在178.5摄氏度及更高温度下会变成清澈的液体。这种浑浊的液体似乎具有双折射性。很快,许多这类所谓的“液晶”被发现;1908年,哈雷的有机化学教授D. 福伦德描述了250多种这类物质。亚琛(1885年)、德累斯顿(1888年)和卡尔斯鲁厄(1889年)的物理学教授O. 莱曼在雷尼泽观察到之后,立即开始对这些液晶进行系统研究。在荷兰,阿姆斯特丹的物理化学教授H. W. 巴克斯·鲁泽博姆对液晶感兴趣,特别是因为它们在他的相体系中的地位。当时在赞丹(靠近阿姆斯特丹)的一所中学教化学并在阿姆斯特丹大学担任无薪大学讲师(经巴克斯·鲁泽博姆推荐)的F. M. 耶格尔研究了液晶(1906年),一些博士生也进行了研究(A. C. 德科克,1903年;A. 普林斯,1907年)。在乌得勒支大学,物理学教授L. S. 奥恩斯坦在他的研究计划中给予液晶研究突出地位。液晶似乎能够生长、移动、分裂、交配等,这一发现引发了关于这些物质本质的讨论。莱曼一次又一次地称它们为“看似有生命的晶体”,尽管并没有将它们视为“真正的生物”。在他的《液态晶体与生命理论》(1906年)一书中,莱曼被证明是生物学家E. 海克尔一元论观点的明显支持者。海克尔认为液晶的存在证明了他坚信的无机世界和有机世界之间的统一性。在他的最后一本书《晶体灵魂:关于无机生命的研究》(公元1917年)中,他认为液晶是一种真正生命形式,矿物学和岩石学教授F. 林内直到20世纪30年代也持同样观点。

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