稳定的大环和连接供体-受体体系。分子内联吡啶鎓和四硫富瓦烯组装体。
Stable Macrocyclic and Tethered Donor-Acceptor Systems. Intramolecular Bipyridinium and Tetrathiafulvalene Assemblies.
作者信息
Simonsen Klaus B., Zong Kyukwan, Rogers Robin D., Cava Michael P., Becher Jan
机构信息
Department of Chemistry, Odense University, Campusvej 55, DK-5230 Odense M, Denmark.
出版信息
J Org Chem. 1997 Feb 7;62(3):679-686. doi: 10.1021/jo961782a.
PMID:11671464
Abstract
A series of compounds has been prepared in which a tetrathiafulvalene (TTF)-derived donor is covalently tethered or bridged to one or more bipyridinium (viologen) acceptors. The relative degree of charge transfer observed in this series is discussed as a function of structure. The greatest CT effect is seen in the cyclophanes 9a-c and 13.
摘要
已经制备了一系列化合物，其中基于四硫富瓦烯（TTF）的供体与一个或多个联吡啶鎓（紫精）受体共价 tethered 或桥连。讨论了该系列中观察到的电荷转移的相对程度与结构的关系。在环番 9a - c 和 13 中观察到最大的 CT 效应。 （注：“tethered”此处不太明确准确意思，可能是“连接”之类的意思，但保留原文更准确。）
Zotero 插件