基于四硫富瓦烯和二烷基紫精的分子复合物。
Molecular complexes based on tetrathiafulvalene and dialkylviologens.
作者信息
Rahman Bilkish, Akutsu Hiroki, Yamada Jun-ichi, Nakatsuji Shin'ichi
机构信息
Graduate School of Material Science, University of Hyogo, 3-2-1 Kouto, Kamigori, Hyogo 678-1297, Japan.
出版信息
Molecules. 2007 Apr 27;12(4):853-60. doi: 10.3390/12040853.
Abstract
Three kinds of molecular complexes based on tetrathiafulvalene (TTF) and dialkylviologens were prepared and their crystal structures elucidated. While TTF-dimethylviologen complex forms a mixed stack arrangement of donors and acceptors in its crystal structure, TTF donors aggregate with long alkyl groups by CH/pi and/or van der Waals interactions in a couple of TTF-heptylviologen complexes.
摘要
制备了三种基于四硫富瓦烯（TTF）和二烷基紫精的分子复合物，并阐明了它们的晶体结构。在其晶体结构中，TTF-二甲基紫精复合物形成了供体和受体的混合堆积排列，而在一些TTF-庚基紫精复合物中，TTF供体通过CH/π和/或范德华相互作用与长烷基聚集在一起。
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