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随机杂聚物动力学

Random heteropolymer dynamics.

作者信息

Konkoli Z, Hertz J, Franz S

机构信息

NORDITA, Blegdamsvej 17, DK 2100 København, Denmark.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2001 Nov;64(5 Pt 1):051910. doi: 10.1103/PhysRevE.64.051910. Epub 2001 Oct 25.

Abstract

We study the Langevin dynamics of the standard random heteropolymer model by mapping the problem to a supersymmetric field theory using the Martin-Siggia-Rose formalism. The resulting model is solved nonperturbatively employing a Gaussian variational approach. In constructing the solution, we assume that the chain is very long and impose the translational invariance which is expected to be present in the bulk of the globule by averaging over the center of mass coordinate. In this way we derive equations of motion for the correlation and response functions C(t,t') and R(t,t'). The order parameters are extracted from the asymptotic behavior of these functions. We find a dynamical phase diagram with frozen (glassy) and melted (ergodic) phases. In the glassy phase the system fails to reach equilibrium and exhibits aging of the type found in p-spin glasses. Within the approximations used in this study, the random heteropolymer model can be mapped to the problem of a manifold in a random potential with power law correlations.

摘要

我们通过使用马丁 - 西格西亚 - 罗斯形式体系将问题映射到一个超对称场论来研究标准随机杂聚物模型的朗之万动力学。所得模型采用高斯变分方法进行非微扰求解。在构建解的过程中,我们假设链非常长,并通过对质心坐标进行平均来施加平移不变性,这种平移不变性预计存在于球状体的主体部分。通过这种方式,我们推导了关联函数(C(t,t'))和响应函数(R(t,t'))的运动方程。序参量从这些函数的渐近行为中提取。我们发现了一个具有冻结(玻璃态)和熔化(遍历态)相的动力学相图。在玻璃态相中,系统无法达到平衡,并表现出与(p) - 自旋玻璃中发现的那种老化现象。在本研究中所使用的近似范围内,随机杂聚物模型可以映射到具有幂律关联的随机势中的流形问题。

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