Lin Q, Chen Y, Chen H, Zheng C
Department of Environmental Science, Zhejiang University, Hangzhou 310029.
Ying Yong Sheng Tai Xue Bao. 2001 Aug;12(4):619-22.
The interaction between organic acids (citric and oxalic acids) and heavy metals was examined in this paper. Equilibrium dialysis showed that the extent organic acids bound metals depended on the metal involved, and their binding properties affected the adsorption of Pb and Cd by soil, which was increased in the presence of oxalic acid, and decreased in the presence of citric acid. The effect of citric acid on the behavior and toxicity of Pb and Cd to plants was also studied. The presence of citric acid could reduce the toxicity of Pb, and inhibit the uptake of Cd in shoots and roots. However, there was no significant effect on the apparent toxicity of Cd. The interaction between Pb and Cd was found to be complicated. The Pb content in rice was higher in the presence of Cd, while the content of Cd is lower in the presence of Pb.
本文研究了有机酸(柠檬酸和草酸)与重金属之间的相互作用。平衡透析表明,有机酸与金属的结合程度取决于所涉及的金属,它们的结合特性影响土壤对铅和镉的吸附,草酸存在时吸附增加,柠檬酸存在时吸附减少。还研究了柠檬酸对铅和镉对植物的行为及毒性的影响。柠檬酸的存在可降低铅的毒性,并抑制镉在地上部和根部的吸收。然而,对镉的表观毒性没有显著影响。发现铅和镉之间的相互作用很复杂。镉存在时水稻中的铅含量较高,而铅存在时镉的含量较低。