Papadopoulou-Mourkidou E, Patsias J, Papadakis E, Koukourikou A
Pesticides Science Laboratory, Aristotle University of Thessaloniki, Ellas, Greece.
Fresenius J Anal Chem. 2001 Oct;371(4):491-6. doi: 10.1007/s002160100934.
Caffeine and selected aniline and phenol compounds have been monitored in the river, lake, and ground water of Northern Greece (Macedonia-Thrace) from September 1999 to December 2000 by means of a fully automated on-line SPE-HPLC method. Among the target aniline and phenol compounds the most abundant was 2,6-di-tert-butyl-4-methylphenol, which was found to be present in both surface and ground water samples. Caffeine was also very frequently present in river and ground water, although its presence in lake water was rare. Caffeine and 2,6-di-tert-butyl-4-methylphenol were also monitored by off-line SPE of water samples and GC-ion-trap MS analysis of extracts.
1999年9月至2000年12月期间，采用全自动在线固相萃取-高效液相色谱法对希腊北部（马其顿-色雷斯）的河流、湖泊和地下水中的咖啡因以及选定的苯胺和苯酚化合物进行了监测。在所监测的苯胺和苯酚化合物中，含量最高的是2,6-二叔丁基-4-甲基苯酚，在地表水和地下水样本中均有发现。咖啡因在河水和地下水中也很常见，不过在湖水中很少见。还通过对水样进行离线固相萃取以及对提取物进行气相色谱-离子阱质谱分析，对咖啡因和2,6-二叔丁基-4-甲基苯酚进行了监测。
