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1,4,7,10-四(2,2'-联吡啶-5-基甲基-双(2,2'-联吡啶)钌(II))-1,4,7,10-四氮杂环十二烷,一种用于带正电物种的大环传感器。

1,4,7,10-tetrakis(2,2'-bipyridyl-5-ylmethyl-bis(2,2'-bipyridine) ruthenium(II))-1,4,7,10-tetraazacyclododecane, a macrocyclic sensor for positively charged species.

作者信息

Josceanu A M, Moore P, Smith S

机构信息

Department of Analytical Chemistry, University Politehnica Bucharest, 1-5 Polizu Street, Bucharest, Romania.

出版信息

Ann Chim. 2001 Sep-Oct;91(9-10):517-30.

PMID:11774841
Abstract

The luminescent behavior of the cyclen-based macrocycle L1 was investigated to establish its sensing ability for protons and transition metal ions. It acts as a good pH sensor in the neutral region. Its interaction with Cu (II) and Ni (II) is accompanied by quenching. The rate data for the interaction with Cu (II) were measured at pH 7.43.

摘要

研究了基于环糊精的大环化合物L1的发光行为,以确定其对质子和过渡金属离子的传感能力。它在中性区域是一种良好的pH传感器。它与铜(II)和镍(II)的相互作用伴随着猝灭。在pH 7.43下测量了与铜(II)相互作用的速率数据。

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