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Stretched polymers in a poor solvent.

作者信息

Grassberger Peter, Hsu Hsiao-Ping

机构信息

John-von-Neumann Institute for Computing, Forschungszentrum Jülich, D-52425 Jülich, Germany.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2002 Mar;65(3 Pt 1):031807. doi: 10.1103/PhysRevE.65.031807. Epub 2002 Mar 7.

Abstract

Stretched polymers with attractive interaction are studied in two and three dimensions. They are described by biased self-avoiding random walks with nearest-neighbor attraction. The bias corresponds to opposite forces applied to the first and last monomers. We show that both in d=2 and d=3 a phase transition occurs as this force is increased beyond a critical value, where the polymer changes from a collapsed globule to a stretched configuration. This transition is second order in d=2 and first order in d=3. For d=2 we predict the transition point quantitatively from properties of the unstretched polymer. This is not possible in d=3, but even there we can estimate the transition point precisely, and we can study the scaling at temperatures slightly below the collapse temperature of the unstretched polymer. We find very large finite size corrections that would make very difficult the estimate of the transition point from straightforward simulations.

摘要

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