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Electrospray ionization tandem mass spectrometric characteristics and fragmentation mechanisms of distamycin analogues.

作者信息

Tang Feili, Wang Jin, Liu Dan, Yuan Gu, Liu Yen, Jin Zhu Chang, Fen Zhao Yu

机构信息

Department of Chemical Biology, The Key Laboratory of Bioorganic Chemistry and Molecular Engineering, Ministry of Education, College of Chemistry, Peking University, Beijing 100871, PR China.

出版信息

Rapid Commun Mass Spectrom. 2002;16(11):1035-9. doi: 10.1002/rcm.680.

Abstract

The electrospray ionization tandem mass spectrometric (ESI-MS/MS) characteristics and fragmentation mechanisms of eight distamycin analogues containing N-methylpyrrole and N-methylimidazole were investigated. The members of two isomeric groups of distamycin analogues with the same elemental composition can be distinguished by MS/MS spectra of protonated molecules and of significant fragment ions.

摘要

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