Frey H Christopher, Bammi Sachin
Department of Civil Engineering, North Carolina State University, Raleigh 27695-7908, USA.
J Air Waste Manag Assoc. 2002 Apr;52(4):435-48. doi: 10.1080/10473289.2002.10470792.
Variability refers to real differences in emissions among multiple emission sources at any given time or over time for any individual emission source. Variability in emissions can be attributed to variation in fuel or feedstock composition, ambient temperature, design, maintenance, or operation. Uncertainty refers to lack of knowledge regarding the true value of emissions. Sources of uncertainty include small sample sizes, bias or imprecision in measurements, nonrepresentativeness, or lack of data. Quantitative methods for characterizing both variability and uncertainty are demonstrated and applied to case studies of emission factors for lawn and garden (L&G) equipment engines. Variability was quantified using empirical and parametric distributions. Bootstrap simulation was used to characterize confidence intervals for the fitted distributions. The 95% confidence intervals for the mean grams per brake horsepower/hour (g/hp-hr) emission factors for two-stroke engine total hydrocarbon (THC) and NOx emissions were from -30 to +41% and from -45 to +75%, respectively. The confidence intervals for four-stroke engines were from -33 to +46% for THCs and from -27 to +35% for NOx. These quantitative measures of uncertainty convey information regarding the quality of the emission factors and serve as a basis for calculation of uncertainty in emission inventories (EIs).
变异性是指在任何给定时间,多个排放源之间排放的实际差异,或者对于任何单个排放源而言,随时间推移排放的实际差异。排放的变异性可归因于燃料或原料成分、环境温度、设计、维护或运行方面的变化。不确定性是指对排放真实值缺乏了解。不确定性的来源包括样本量小、测量中的偏差或不精确性、缺乏代表性或数据不足。本文展示了表征变异性和不确定性的定量方法,并将其应用于草坪和园艺(L&G)设备发动机排放因子的案例研究。变异性通过经验分布和参数分布进行量化。使用自助模拟来表征拟合分布的置信区间。两冲程发动机总碳氢化合物(THC)和氮氧化物(NOx)排放的每制动马力每小时平均克数(g/hp-hr)排放因子的95%置信区间分别为-30%至+41%和-45%至+75%。四冲程发动机THC的置信区间为-33%至+46%,NOx的置信区间为-27%至+35%。这些不确定性的定量度量传达了有关排放因子质量的信息,并作为计算排放清单(EI)不确定性的基础。