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[从多花飞蓬中分离并鉴定6'-O-咖啡酰飞蓬苷的结构]

[Isolation and structure of 6'-O-caffeylerigeroside from Erigeron multiradiatus].

作者信息

Zhang Y, Li L, Yang P, Zhang H

机构信息

School of Pharmacy, West China University of Medical Sciences, Chengdu 610041.

出版信息

Yao Xue Xue Bao. 1998 Nov;33(11):836-8.

Abstract

The plant, Erigeron multiradiatus (Wall.) Benth(Family: Compositae), is a perennial herb distributed abundantly in the mountainous area of the southwestern part in China. It is used in folk medicine for the treatment of common cold, panting cough, rheumatic, enteritis and toothache. In this paper, we report a new glycoside named as 6'-O-caffeylerigeroside isolated from Erigeron Multiradiatus (Family: Compositae) together with four known compounds. The known compounds were identified as pyromeconic acid(I), scopoletin(II), 4-hydroxybenzoic acid(III) and vanillic acid(IV). The structure of 6'-O-caffeylerigeroside was elucidated as gamma-pyrone-3-O-[6"-(3',4'-dihydroxy-cinnamoyl)]-beta-D-glucoside(V) on the basis of chemical evidence and spectral data.

摘要

植物多花飞蓬(Erigeron multiradiatus (Wall.) Benth,菊科)是一种多年生草本植物,在中国西南部山区广泛分布。它在民间医学中用于治疗感冒、气喘咳嗽、风湿、肠炎和牙痛。本文中,我们报道了从多花飞蓬(菊科)中分离得到的一种名为6'-O-咖啡酰飞蓬苷的新糖苷以及四种已知化合物。这些已知化合物分别被鉴定为焦袂康酸(I)、东莨菪素(II)、4-羟基苯甲酸(III)和香草酸(IV)。基于化学证据和光谱数据,6'-O-咖啡酰飞蓬苷的结构被阐明为γ-吡喃酮-3-O-[6"-(3',4'-二羟基肉桂酰)]-β-D-葡萄糖苷(V)。

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