Koreneva L G, Zolin V F, Serbinova T A
Biofizika. 1975 Sep-Oct;20(5):767-71.
Circular dichroism of pyrodoxalidenaminoacid complexes with rare earths and other metals and magnetic circular dichroism of several neodimium complexes are investigated. CD spectra of the complexes of the rare earths with azometines made of different amino acids could be classified into four groups. Some of the CD spectra are shown to be individual. The dependence of the CD spectra on the rare earch ion dimension is considered. Coordination of the rare earth ions is shown to be the same as in the case of zinc, cobalt, iron or copper.
研究了吡哆醛亚胺氨基酸与稀土及其他金属形成的配合物的圆二色性以及几种钕配合物的磁圆二色性。稀土与由不同氨基酸制成的偶氮甲碱形成的配合物的圆二色光谱可分为四类。部分圆二色光谱显示具有独特性。考虑了圆二色光谱对稀土离子尺寸的依赖性。结果表明,稀土离子的配位情况与锌、钴、铁或铜的情况相同。