通过开环易位聚合制备的多相碳-碳偶联和聚合催化剂。
Heterogeneous C-C coupling and polymerization catalysts prepared by ROMP.
作者信息
Buchmeiser Michael R
机构信息
Institute of Analytical Chemistry and Radiochemistry, University of Innsbruck, Innrain 52 a, Austria.
出版信息
Bioorg Med Chem Lett. 2002 Jul 22;12(14):1837-40. doi: 10.1016/s0960-894x(02)00275-5.
This contribution summarizes the latest developments in the area of catalytic supports prepared via ring-opening metathesis polymerization (ROMP). In particular, the synthesis of heterogeneous catalytic systems active in Pd-mediated C-C coupling reactions such as Heck, Sonogashira-Hagihara and Suzuki couplings, as well as in ruthenium-mediated olefin metathesis reactions will be summarized. The general concept for the synthesis of these supports will be outlined in detailed.
本论文综述了通过开环易位聚合（ROMP）制备催化载体领域的最新进展。特别地，将总结在钯介导的碳-碳偶联反应（如Heck反应、Sonogashira-Hagihara反应和Suzuki偶联反应）以及钌介导的烯烃复分解反应中具有活性的多相催化体系的合成。将详细概述这些载体合成的一般概念。
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