作为催化模块化配体的聚合物负载1-芳基-3-烷基三氮烯。第2部分：筛选具有催化活性的固定化金属配合物。
Polymer-bound 1-aryl-3-alkyltriazenes as modular ligands for catalysis. Part 2: screening immobilized metal complexes for catalytic activity.
作者信息
Bräse Stefan, Dahmen Stefan, Lauterwasser Frank, Leadbeater Nicholas E, Sharp Emma L
机构信息
Kekulé-Institut für Organische Chemie und Biochemie der Rheinischen Friedrich-Wilhelms-Universität Bonn, Gerhard-Domagk-Strasse. 1, Germany.
出版信息
Bioorg Med Chem Lett. 2002 Jul 22;12(14):1849-51. doi: 10.1016/s0960-894x(02)00279-2.
A range of polymer-supported triazenes and their metal-bound analogues were screened for use in catalysis. Fe, Cu and Zr complexes were, together with the polymer-supported triazene ligand alone, screened in the addition of Et(2)Zn to benzaldehyde. A supported Pd triazene complex was screened for activity in Suzuki and Sonogashira reactions and a supported Ru triazene complex screened for transfer hydrogenation.
筛选了一系列聚合物负载的三氮烯及其金属结合类似物用于催化。铁、铜和锆配合物，以及单独的聚合物负载三氮烯配体，在将二乙基锌添加到苯甲醛的反应中进行了筛选。筛选了一种负载型钯三氮烯配合物在铃木反应和 Sonogashira 反应中的活性，以及一种负载型钌三氮烯配合物在转移氢化反应中的活性。
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