有机合成中的张力硅杂环：一种用于醛对映选择性烯丙基化反应的新型试剂。
Strained silacycles in organic synthesis: a new reagent for the enantioselective allylation of aldehydes.
作者信息
Kinnaird James W A, Ng Pui Yee, Kubota Katsumi, Wang Xiaolun, Leighton James L
机构信息
Department of Chemistry, Columbia University, New York, New York 10027, USA.
出版信息
J Am Chem Soc. 2002 Jul 10;124(27):7920-1. doi: 10.1021/ja0264908.
PMID:12095334
Abstract
A new reagent for the enantioselective allylation of aliphatic aldehydes has been developed. The reagent is easily prepared in a single step from commercially available materials and may be stored without significant decomposition. The reactivity of the reagent is attributed to strain-release Lewis acidity.
摘要
一种用于脂肪族醛对映选择性烯丙基化反应的新型试剂已被开发出来。该试剂可通过市售原料一步轻松制备，且可储存而无明显分解。该试剂的反应活性归因于应变释放路易斯酸性。
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