活性硝基乙烯衍生物的竞争狄尔斯-阿尔德反应及环加合物的[3,3] -σ迁移重排。
Competing Diels-Alder reactions of activated nitroethylene derivatives and [3,3]-sigmatropic rearrangements of the cycloadducts.
作者信息
Wade Peter A, Murray James K, Shah-Patel Sharmila, Le Hung T
机构信息
Department of Chemistry, Drexel University, Philadelphia, PA 19104, USA.
出版信息
Chem Commun (Camb). 2002 May 21(10):1090-1. doi: 10.1039/b200224h.
DOI:10.1039/b200224h
PMID:12122679
Abstract
Diels-Alder reaction of nitroethylene derivatives with cyclohexa-1,3-diene afforded three pericyclic products some of which could be converted to others via a new [3,3]-sigmatropic rearrangement or via a Claisen rearrangement.
摘要
硝基乙烯衍生物与环己-1,3-二烯的狄尔斯-阿尔德反应生成了三种周环产物，其中一些产物可通过一种新的[3,3] - 迁移重排或克莱森重排转化为其他产物。
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