Frost Ray L, Kloprogge J Theo, Ding Zhe
Centre for Instrumental and Developmental Chemistry, Queensland University of Technology, Brisbane, Australia.
Spectrochim Acta A Mol Biomol Spectrosc. 2002 Jul;58(9):1881-94. doi: 10.1016/s1386-1425(01)00638-2.
FTIR and Infrared emission spectroscopy (IES) has been used to characterise the Uley (Australian) and Garfield nontronites. These clay minerals are characterised by a strong emission band at 3570 cm(-1) attributed to the FeFeOH unit. Dehydroxylation is followed by the loss of intensity of this band as a function of temperature. Dehydroxylation is also followed by the loss of intensity of the FeFeOH deformation vibration at 843 cm(-1). IES shows that the dehydroxylation occurs as a continuous process in comparison to DTA/TGA studies where the dehydroxylation occurs abruptly at 425 degrees C. Water in these high iron bearing smectites have been observed through the stretching mode at 3430 cm(-1) and the bending mode at 1630 cm(-1). Different types of water are identified in the nontronite structure by the analysis of the band profile in the 1590-1680 cm(-1) region. Low frequency vibrations show that the Uley green nontronite is similar to the Garfield nontronite. The brown Uley nontronite is closer to the Hohen-Hagen nontronite. The Uley nontronites may, therefore, be used spectroscopically to replace other nontronites as a reference clay mineral.
