Stereoselective synthesis of (+)-boronolide.
作者信息
Carda Miguel, Rodríguez Santiago, Segovia Beatriz, Marco J Alberto
机构信息
U. P. de Química Inorgánica y Orgánica, Universidad Jaume I, E-12080 Castellón, Spain.
出版信息
J Org Chem. 2002 Sep 6;67(18):6560-3. doi: 10.1021/jo025813f.
PMID:12201784
Abstract
The delta-lactone boronolide (+)-1, a pharmacologically active, naturally occurring product, has been synthesized in enantiopure form with L-erythrulose as the chiral starting material. The key steps of the synthesis were a highly stereoselective aldol-reduction one-pot sequence, an indium-mediated diastereoselective aldehyde allylation, and a ring-closing metathesis.
摘要
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引用本文的文献
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正确译文：sporioxin A的首次全合成。
如果原文确定是“sporiolide A”，则译文为：sporiolide A的首次全合成。
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