脂肪酶催化的（±）-顺式黄烷-4-醇及其乙酸酯的动力学拆分：手性3-羟基黄烷酮的合成
Lipase-catalyzed kinetic resolution of (+/-)-cis-flavan-4-ol and its acetate: synthesis of chiral 3-hydroxyflavanones.
作者信息
Todoroki Tamotsu, Saito Akiko, Tanaka Akira
机构信息
College of Technology, Toyama Prefectural University, Kosugi, Japan.
出版信息
Biosci Biotechnol Biochem. 2002 Aug;66(8):1772-4. doi: 10.1271/bbb.66.1772.
PMID:12353646
Abstract
Lipase-catalyzed kinetic resolution of (+/-)-cis-flavan-4-ol and its acetate led to enantiomerically enriched flavan-4-ol and its acetate. These chiral compounds were converted to (2R, 3R)- and (25, 3S)-3-hydroxyflavanones.
摘要
脂肪酶催化的（±）-顺式黄烷-4-醇及其乙酸酯的动力学拆分产生了对映体富集的黄烷-4-醇及其乙酸酯。这些手性化合物被转化为（2R，3R）-和（2S，3S）-3-羟基黄烷酮。
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