肟草酸酰胺的制备及其在自由基介导的内酰胺合成中的应用。
Preparation of oxime oxalate amides and their use in free-radical mediated syntheses of lactams.
作者信息
Scanlan Eoin M, Walton John C
机构信息
University of St. Andrews, School of Chemistry, St. Andres, Fife, UK KY16 9ST.
出版信息
Chem Commun (Camb). 2002 Sep 21(18):2086-7. doi: 10.1039/b205962b.
DOI:10.1039/b205962b
PMID:12357791
Abstract
Photosensitized decomposition of oxime oxalate amides is a useful new route to carbamoyl radicals that may cyclise to afford beta- or gamma-lactams.
摘要
草酸肟酰胺的光敏分解是生成氨基甲酰基自由基的一条有用的新途径，该自由基可环化生成β-或γ-内酰胺。
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