Evidence of short-time dynamical correlations in simple liquids.

We report a molecular dynamics study of the collective dynamics of a simple monatomic liquid--interacting through a two-body potential that mimics that of lithium--across the liquid-glass transition. In the glassy phase we find evidences of a fast relaxation process similar to that recently found in Lennard-Jones glasses. The origin of this process is ascribed to the topological disorder, i.e., to the dephasing of the different momentum Q Fourier components of the actual normal modes of vibration of the disordered structure. More important, we find that the fast relaxation persists in the liquid phase with almost no temperature dependence of its characteristic parameters (strength and relaxation time). We conclude, therefore, that in the liquid phase well above the melting point, at variance with the usual assumption of uncorrelated binary collisions, the short time particle motion is strongly correlated and can be described via a normal mode expansion of the atomic dynamics.