Shirakawa Eiji, Takahashi Go, Tsuchimoto Teruhisa, Kawakami Yusuke
Graduate School of Materials Science, Japan Advanced Institute of Science and Technology, Asahidai, Tatsunokuchi, Ishikawa 923-1292, Japan.
Chem Commun (Camb). 2002 Oct 7(19):2210-1. doi: 10.1039/b207185a.
Aryl- and alkenylboronates were found to add to 1,3-dienes in the presence of a catalytic amount of bis(1,5-cyclooctadiene)nickel, where a proton source in combination with a solvent considerably controls the regioselectivity.
发现在催化量的双（1,5 - 环辛二烯）镍存在下，芳基硼酸酯和烯基硼酸酯可与1,3 - 二烯加成，其中质子源与溶剂相结合可显著控制区域选择性。
