室温离子液体中可逆加成-断裂链转移（RAFT）聚合的首次报道。
First report of reversible addition-fragmentation chain transfer (RAFT) polymerisation in room temperature ionic liquids.
作者信息
Perrier Sébastien, Davis Thomas P, Carmichael Adrian J, Haddleton David M
机构信息
Centre for Advanced Macromolecular Design, School of Chemical Engineering & Industrial Chemistry, University of New South Wales, NSW, 2052 Sydney, Australia.
出版信息
Chem Commun (Camb). 2002 Oct 7(19):2226-7. doi: 10.1039/b206534g.
The Reversible Addition-Fragmentation chain Transfer (RAFT) polymerisation of acrylates, methacrylates and styrene is reported for the first time in room temperature ionic liquids; the acrylate and methacrylate polymerisations show a living character and lead to well-characterised polymers, with narrow polydispersity (< 1.3); in the case of styrene, the insolubility of the polymer in the ionic liquids stops the polymerisation at an early stage.
首次报道了在室温离子液体中进行丙烯酸酯、甲基丙烯酸酯和苯乙烯的可逆加成-断裂链转移（RAFT）聚合反应；丙烯酸酯和甲基丙烯酸酯的聚合反应表现出活性特征，并生成了具有良好表征的聚合物，其多分散性较窄（<1.3）；对于苯乙烯，聚合物在离子液体中的不溶性导致聚合反应在早期阶段就停止了。
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