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β-烷基铃木-宫浦交叉偶联反应:发展、机理研究及其在天然产物合成中的应用 文章末尾可找到缩写列表。

The B-Alkyl Suzuki-Miyaura Cross-Coupling Reaction: Development, Mechanistic Study, and Applications in Natural Product Synthesis A list of abbreviations can be found at the end of the article.

作者信息

Chemler Sherry R., Trauner Dirk, Danishefsky Samuel J.

机构信息

Laboratory of Bioorganic Chemistry, Sloan-Kettering Institute for Cancer Research 1275 York Ave., Box 106, New York, NY 10021.

出版信息

Angew Chem Int Ed Engl. 2001 Dec 17;40(24):4544-4568. doi: 10.1002/1521-3773(20011217)40:24<4544::aid-anie4544>3.0.co;2-n.

DOI:10.1002/1521-3773(20011217)40:24<4544::aid-anie4544>3.0.co;2-n
PMID:12404358
Abstract

The development of new reactions that facilitate the creative and efficient synthesis of molecular structures with desirable properties continues to fascinate chemists. The test of a significant contribution is its acceptance over time by the scientific community. The B-alkyl Suzuki-Miyaura cross-coupling reaction appears to be one such reaction. Since its disclosure by Suzuki and Miyaura in 1986, this reaction has been an attractive solution to challenging synthetic problems.

摘要

开发能够促进创造性且高效地合成具有理想性质的分子结构的新反应,一直吸引着化学家们。一项重大贡献的检验标准是随着时间的推移它被科学界所接受。B-烷基铃木-宫浦交叉偶联反应似乎就是这样一种反应。自1986年铃木和宫浦披露该反应以来,它一直是解决具有挑战性的合成问题的一种有吸引力的方法。

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