远端二烷基化杯[4]芳烃与1-氯-4-(三氟甲基)苯主客体相互作用的各向异性衰减研究
Anisotropy decay study on the host-guest interaction of distally dialkylated calix[4]arenes with 1-chloro-4-(trifluoromethyl)benzene.
作者信息
Kunsági-Máté Sándor, Bitter István, Grün Alajos, Nagy Géza, Kollár László
机构信息
Department of General and Physical Chemistry, University of Pécs, Ifjúság 6., 7624, Pécs Hungary.
出版信息
J Biochem Biophys Methods. 2002 Oct-Nov;53(1-3):101-8. doi: 10.1016/s0165-022x(02)00097-0.
The 'host' properties of distally dialkylated calix[4]arenes and 4-tert-butylcalix[4]arenes in the presence of 1-chloro-4-(trifluoromethyl)benzene (BFT) were studied in chloroform solvent by intensity-independent spectrofluorometric method. The anisotropy decay experiments were found as suitable method to indicate the host-guest complex formation but it is unable to determine the strength of supramolecular interaction.
在氯仿溶剂中，采用强度无关荧光光谱法研究了远端二烷基化杯[4]芳烃和4-叔丁基杯[4]芳烃在1-氯-4-（三氟甲基）苯（BFT）存在下的“主体”性质。各向异性衰减实验被发现是指示主客体复合物形成的合适方法，但它无法确定超分子相互作用的强度。
Zotero 插件