均三氧杂杯[3]芳烃上缘的修饰以及硝基均三氧杂杯[3]芳烃衍生物与正己胺之间的络合作用。
Modification of the upper rim of homooxacalix[3]arenes and complexation between a nitrohomooxacalix[3]arene derivative and n-hexylamine.
作者信息
Tsubaki Kazunori, Otsubo Tadamune, Morimoto Tatsuya, Maruoka Hiromi, Furukawa Mika, Momose Yashima, Shang Muhong, Fuji Kaoru
机构信息
Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
出版信息
J Org Chem. 2002 Nov 15;67(23):8151-6. doi: 10.1021/jo026152p.
PMID:12423145
Abstract
Several functional groups were introduced on the upper rim of (lower rim free) homooxacalix[3]arene for the first time. The swinging nitrohomooxacalix[3]arene host 1 was fixed in the cone conformation by complexation with n-hexylamine.
摘要
首次在（下缘自由的）同氧杂杯[3]芳烃的上缘引入了几个官能团。摆动的硝基亚同氧杂杯[3]芳烃主体1通过与正己胺络合而固定在锥状构象中。
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