Sibert John W, Forshee Philip B
Department of Chemistry, The University of Texas at Dallas, P.O. Box 830688, Richardson, Texas 75083-0688, USA.
Inorg Chem. 2002 Nov 18;41(23):5928-30. doi: 10.1021/ic0259235.
A hybrid, macrocyclic structure based on o-phenylenediamine and a crown ether promotes an intimate mutual interaction with a bound potassium ion in the form of chelation by the redox-active moiety. A general synthetic method and properties are described for the first member of a new class of redox-active, lariat-type macrocycles called the "o-Wurster's crowns".
一种基于邻苯二胺和冠醚的杂化大环结构，通过氧化还原活性部分以螯合的形式促进与结合钾离子的紧密相互作用。本文描述了一类新型氧化还原活性套索型大环化合物（称为“邻伍斯特冠醚”）首个成员的通用合成方法及其性质。
